Liquid electrode plasma-optical emission spectrometry combined with solid-phase preconcentration for on-site analysis of lead

フォーマット:

論文

責任表示:

牧, 輝弥 ; 長谷川, 浩

言語:

英語

出版情報:

Elsevier B.V., 2017-08-15

著者名:

• 牧, 輝弥
• 長谷川, 浩

掲載情報:

Journal of Chromatography B: Analytical Technologies in the Biomedical and Life Sciences

ISSN:

1570-0232      

巻:

1060

開始ページ:

190

終了ページ:

199

バージョン:

author

概要:

A relatively rapid and precise method is presented for the determination of lead in aqueous matrix. The method consists of analyte quantitation using the liquid electrode plasma-optical emission spectrometry (LEP-OES) coupled with selective … separation/preconcentration by solid-phase extraction (SPE). The impact of operating variables on the retention of lead in SPEs such as pH, flow rate of the sample solution; type, volume, flow rate of the eluent; and matrix effects were investigated. Selective SPE-separation/preconcentration minimized the interfering effect due to manganese in solution and limitations in lead-detection in low-concentration samples by LEP-OES. The LEP-OES operating parameters such as the electrical conductivity of sample solution; applied voltage; on-time, off-time, pulse count for applied voltage; number of measurements; and matrix effects have also been optimized to obtain a distinct peak for the lead at λmax = 405.8 nm. The limit of detection (3σ) and the limit of quantification (10σ) for lead determination using the technique were found as 1.9 and 6.5 ng mL−1, respectively. The precision, as relative standard deviation, was lower than 5% at 0.1 μg mL−1 Pb, and the preconcentration factor was found to be 187. The proposed method was applied to the analysis of lead contents in the natural aqueous matrix (recovery rate: >95%). The method accuracy was verified using certified reference material of wastewaters: SPS-WW1 and ERM-CA713. The results from LEP-OES were in good agreement with inductively coupled plasma optical emission spectrometry measurements of the same samples. The application of the method is rapid (≤5 min, without preconcentration) with a reliable detection limit at trace levels. © 2017 Elsevier B.V.<br />著者所属: 金沢大学理工研究域物質化学系<br />Embargo Period 12 months 続きを見る

URL:

http://hdl.handle.net/2297/00048858