Regioselective photoalkylation of 2-cyano-6-methoxynaphthalene by methoxy-substituted 1,2-diarylcyclopropanes

Regioselective photoalkylation of 2-cyano-6-methoxynaphthalene by methoxy-substituted 1,2-diarylcyclopropanes

フォーマット:

論文

責任表示:

Maeda, Hajime ; Matsuda, Shoji ; Mizuno, Kazuhiko

言語:

英語

出版情報:

Elsevier BV, 2009-08-15

著者名:

掲載情報:

Journal of Photochemistry and Photobiology A: Chemistry

ISSN:

1010-6030

巻:

206

通号:

2-3

開始ページ:

129

終了ページ:

133

バージョン:

author

概要:

金沢大学理工研究域物質化学系<br />Photoreactions of 2-cyano-6-methoxynaphthalene with methoxy-substituted 1,2-diarylcyclopropanes in benzene give 2-cyano-1-(1,3-diarylpropyl)-6-methoxynaphthalenes. The excellent regioselectivity seen in these processes can be explained by initial formation of singlet exciplexes, in which the dipoles of each component are oriented in opposite directions. © 2009 Elsevier B.V. All rights reserved.

URL:

http://hdl.handle.net/2297/18991

タイトル・著者・出版者が同じ資料

詳細

主題:	1,2-Diarylcyclopropanes; 2-Cyano-6-methoxynaphthalene; Exciplex; Photoreaction
受理日:	2009-08-15

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