Formation and Stability of Binary Complexes of Divalent Ecotoxic Ions (Ni, Cu, Zn, Cd, Pb) with Biodegradable Aminopolycarboxylate Chelants (dl-2-(2-Carboxymethyl)Nitrilotriacetic Acid, GLDA, and 3-Hydroxy-2,2′-Iminodisuccinic Acid, HIDS) in Aqueous Solutions

Formation and Stability of Binary Complexes of Divalent Ecotoxic Ions (Ni, Cu, Zn, Cd, Pb) with Biodegradable Aminopolycarboxylate Chelants (dl-2-(2-Carboxymethyl)Nitrilotriacetic Acid, GLDA, and 3-Hydroxy-2,2′-Iminodisuccinic Acid, HIDS) in Aqueous Solutions

フォーマット:

論文

責任表示:

Begum, Zinnat A. ; Rahman, Ismail M. M. ; Tate, Yousuke ; Egawa, Yuji ; Maki, Teruya ; Hasegawa, Hiroshi

言語:

英語

出版情報:

Springer Science+Business Media, 2012-11-01

著者名:

掲載情報:

Journal of Solution Chemistry

ISSN:

0095-9782

巻:

41

通号:

10

開始ページ:

1713

終了ページ:

1728

バージョン:

author

概要:

The protonation and complex formation equilibria of two biodegradable aminopolycarboxylate chelants {dl-2-(2-carboxymethyl)nitrilotriacetic acid (GLDA) and 3-hydroxy-2,2′-iminodisuccinic acid (HIDS)} with Ni 2+, Cu 2+, Zn 2+, Cd 2+ and Pb 2+ ions were investigated using the potentiometric method at a constant ionic strength of I = 0.10 mol·dm -3 (KCl) in aqueous solutions at 25 ± 0.1 °C. The stability constants of the … proton-chelant and metal-chelant species for each metal ion were determined, and the concentration distributions of various complex species in solution were evaluated for each ion. The stability constants (log 10K ML) of the complexes containing Ni 2+, Cu 2+, Zn 2+, Cd 2+ and Pb 2+ ions followed the identical order of log 10K CuL > log 10K NiL > log 10K PbL > log 10K ZnL > log 10K CdL for either GLDA (13.03 > 12.74 > 11.60 > 11.52 > 10.31) or HIDS (12.63 > 11.30 > 10.21 > 9.76 > 7.58). In each case, the constants obtained for metal-GLDA complexes were larger than the corresponding constants for metal-HIDS complexes. The conditional stability constants (log 10 {Mathematical expression}) of the metal-chelant complexes containing GLDA and HIDS were calculated in terms of pH, and compared with the stability constants for EDTA and other biodegradable chelants. © 2012 Springer Science+Business Media New York. 続きを見る

URL:

http://hdl.handle.net/2297/32845

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詳細

主題:	Biodegradable aminopolycarboxylate chelant; Ecotoxic ions; GLDA; HIDS; Stability constant
受理日:	2012-11-01

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1 論文 Formation and stability of binary complexes of divalent ecotoxic ions (Ni, Cu, Zn, Cd, Pb) with biodegradable aminopolycarboxylate chelants … Begum, Zinnat A., Rahman, Ismail M. M., Tate, Yousuke, Egawa, Yuji, Maki, Teruya, Hasegawa, Hiroshi Springer Science+Business Media	7 論文 Recovery of indium from end-of-life liquid-crystal display panels using aminopolycarboxylate chelants with the aid of mechanochemical treatment Hasegawa, Hiroshi, Rahman, Ismail M. M., Egawa, Yuji, Sawai, Hikaru, Begum, Zinnat A., Maki, Teruya, Mizutani, Satoshi Elsevier B.V.
2 論文 Complexation behavior of SrII and geochemically-related elements (MgII, CaII, BaII, and YIII) with biodegradable aminopolycarboxylate chelators (GLDA and HIDS) Begun, Zinnat A., Rahman, Ismail M.M., Hasegawa, Hiroshi, 長谷川, 浩 Elsevier B.V.	8 論文 Recovery of indium from end-of-life liquid-crystal display panels using aminopolycarboxylate chelants with the aid of mechanochemical treatment Hasegawa, Hiroshi, Rahman, Ismail M. M., Egawa, Yuji, Sawai, Hikaru, Begum, Zinnat A., Maki, Teruya, Mizutani, Satoshi Elsevier B.V.
3 論文 Stability constants of Fe(III) and Cr(III) complexes with dl-2-(2-carboxymethyl)nitrilotriacetic acid (GLDA) and 3-hydroxy-2,2'- iminodisuccinic acid (HIDS) in … Begum, Zinnat A., Rahman, Ismail M. M., Sawai, Hikaru, Tate, Yousuke, Maki, Teruya, Hasegawa, Hiroshi American Society for Biochemistry and Molecular Biology	9 論文 Recovery of toxic metal ions from washing effluent containing excess aminopolycarboxylate chelant in solution Hasegawa, Hiroshi, Rahman, Ismail M. M., Nakano, Masayoshi, Begum, Zinnat A., Egawa, Yuji, Maki, Teruya, Furusho, … Elsevier
4 論文 Effect of Extraction Variables on the Biodegradable Chelant-Assisted Removal of Toxic Metals from Artificially Contaminated European Reference Soils Begum, Zinnat A., Rahman, Ismail M. M., Sawai, Hikaru, Mizutani, Satoshi, Maki, Teruya, Hasegawa, Hiroshi Springer Science+Business Media	10 論文 Recovery of toxic metal ions from washing effluent containing excess aminopolycarboxylate chelant in solution Hasegawa, Hiroshi, Rahman, Ismail M. M., Nakano, Masayoshi, Begum, Zinnat A., Egawa, Yuji, Maki, Teruya, Furusho, … Elsevier
5 論文 Remediation of toxic metal contaminated soil by washing with biodegradable aminopolycarboxylate chelants Begum, Zinnat A., Rahman, Ismail M. M., Tate, Yousuke, Sawai, Hikaru, Maki, Teruya, Hasegawa, Hiroshi Elsevier	11 論文 Recovery of toxic metal ions from washing effluent containing excess aminopolycarboxylate chelant in solution Hasegawa, Hiroshi, Rahman, Ismail M.M., Nakano, Masayoshi, Begum, Zinnat A., Egawa, Yuji, Maki, Teruya, Furusho, … Elsevier
6 図書 Remediation of toxic metal contaminated soil using biodegradable aminopolycarboxylate chelants Begum, Zinnat Ara [Zinnat Ara Begum]	12 論文 Chelant-induced reclamation of indium from the spent liquid crystal display panels with the aid of microwave irradiation Hasegawa, Hiroshi, Rahman, Ismail M. M., Egawa, Yuji, Sawai, Hikaru, Begum, Zinnat A., Maki, Teruya, Mizutani, Satoshi Elsevier B.V.