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Formation and stability of binary complexes of divalent ecotoxic ions (Ni, Cu, Zn, Cd, Pb) with biodegradable aminopolycarboxylate chelants (dl-2-(2-carboxymethyl)nitrilotriacetic acid, GLDA, and 3-hydroxy-2,2′- iminodisuccinic acid, HIDS) in aqueous solutions
- フォーマット:
- 論文
- 責任表示:
- Begum, Zinnat A. ; Rahman, Ismail M. M. ; Tate, Yousuke ; Egawa, Yuji ; Maki, Teruya ; Hasegawa, Hiroshi
- 言語:
- 英語
- 出版情報:
- Springer Science+Business Media, 2012-11-01
- 著者名:
Begum, Zinnat A. Rahman, Ismail M. M. Tate, Yousuke Egawa, Yuji Maki, Teruya Hasegawa, Hiroshi - 掲載情報:
- Journal of Solution Chemistry
- ISSN:
- 0095-9782
- 巻:
- 41
- 通号:
- 10
- 開始ページ:
- 1713
- 終了ページ:
- 1728
- バージョン:
- author
- 概要:
- The protonation and complex formation equilibria of two biodegradable aminopolycarboxylate chelants {dl-2-(2-carboxymethyl)nitrilotriacetic acid (GLDA) and 3-hydroxy-2,2′-iminodisuccinic acid (HIDS)} with Ni 2+, Cu2+, Zn2+, Cd2+ and Pb 2+ ions were investigated using the potentiometric method at a constant ionic strength of I = 0.10 mol·dm-3 (KCl) in aqueous solutions at 25 ± 0.1 C. The stability constants of the proton-chelant and … metal-chelant species for each metal ion were determined, and the concentration distributions of various complex species in solution were evaluated for each ion. The stability constants (log10 K ML) of the complexes containing Ni2+, Cu2+, Zn2+, Cd2+ and Pb2+ ions followed the identical order of log10 K CuL > log10 K NiL > log10 K PbL > log10 K ZnL > log10 K CdL for either GLDA (13.03 > 12.74 > 11.60 > 11.52 > 10.31) or HIDS (12.63 > 11.30 > 10.21 > 9.76 > 7.58). In each case, the constants obtained for metal-GLDA complexes were larger than the corresponding constants for metal-HIDS complexes. The conditional stability constants (log10 $$ K-{\text{ML}}^{'} $$) of the metal-chelant complexes containing GLDA and HIDS were calculated in terms of pH, and compared with the stability constants for EDTA and other biodegradable chelants. © 2012 Springer Science+Business Media New York. 続きを見る
- URL:
- http://hdl.handle.net/2297/34166
類似資料:
Springer Science+Business Media | |
American Society for Biochemistry and Molecular Biology | |
Springer Science+Business Media | |
[Zinnat Ara Begum] |