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Thermal Reactions of the Nickel(II) Complexes Containing 1-Phenyl-1,2-ethanediamine in the Solid Phase
- フォーマット:
- 論文
- 責任表示:
- Ihara, Yoshinori
- 言語:
- 英語
- 出版情報:
- 日本化学会=The Chemical Society of Japan, 1985-01-01
- 著者名:
- Ihara, Yoshinori
- 掲載情報:
- Bulletin of the Chemical Society of Japan
- ISSN:
- 0009-2673
- 巻:
- 58
- 通号:
- 11
- 開始ページ:
- 3248
- 終了ページ:
- 3251
- バージョン:
- publisher
- 概要:
- Nickel(II) complexes [Ni(phenen)2](ClO4)2 and [Ni(H2O)2(phenen)2]X2 (phenen=1-phenyl-1,2-ethanediamine, X=Cl, Br, or NO3) were prepared, and their thermal behavior was investigated in the solid phase. The nitrate showed a thermochromism consisting of two steps, violet→yellow→violet, which corresponds to a structural change from an octahedral diaqua complex to a square planar anhydride, and then to the octahedral dinitrato complex, respectively. … Both the chloride and bromide were converted into the octahedral dianiono complexes by thermal deaquation-anation, retaining their octahedral configuration. However, no change was observed in the perchlorate, which is invariably square planar. 続きを見る
- URL:
- http://hdl.handle.net/2297/37509
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