A novel synthetic method of pyrrolo[2,3-b]indoles and its application to the synthesis of (±)-debromoflustramine B1

A novel synthetic method of pyrrolo[2,3-b]indoles and its application to the synthesis of (±)-debromoflustramine B1

フォーマット:

論文

責任表示:

Somei, Masanori ; Yamada, Fumio ; Izumi, Tomoyuki ; Nakajou, Masahiro

言語:

英語

出版情報:

日本複素環化学研究所, 1997-01-01

著者名:

掲載情報:

Heterocycles

巻:

45

通号:

12

開始ページ:

2327

終了ページ:

2330

バージョン:

publisher

概要:

金沢大学大学院自然科学研究科生理活性物質科学<br />金沢大学薬学部<br />1-Methoxy-3-(2-nitrovinyl)indole (4) functions as an electrophile and reacted with various nucleophiles regioselectively at the 2-position. Employing allyl alkoxides as nucleophiles, a novel synthetic method of pyrrolo[2,3-b]indoles has been elaborated. Utilizing the method, the synthesis of (±)-debromofIustramine B (10b) was achieved.

URL:

http://hdl.handle.net/2297/4342

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詳細

受理日:	1997-01-01

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3 論文 A convenient synthetic method for 4-nitro-1,3,4,5-tetra-hydrobenz[cd]indoles and its application for an alternative synthesis of (±)-6,7-secoagroclavine Somei, Masanori, Yamada, Fumio, Ohnishi, Hiroyuki, Makita, Yoshihiko, Kuriki, Mikako 日本複素環化学研究所	9 論文 A convenient synthetic method of 2-substituted indoles and its applcation for the synthesis of natural alkaloid, borrerine Somei, Masanori, Sayama, Shinsuke, Naka, Katsumi, Yamada, Fumio 日本複素環化学研究所
4 論文 Preparations of melatonin and 1-hydroxymelatonin, and its novel nucleophilic dimerization to (±)-3a,3a'-bispyrrolo[2,3-b]indoles Somei, Masanori, Oshikiri, Naoki, Hasegawa, Masakazu, Yamada, Fumio 日本複素環化学研究所	10 論文 Synthesis of 3a-(indol-3-yl)-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole core of leptosins D-F based on nucleophilic substitution reaction on indole nucleus Yamada, Fumio, Goto, Aya, Somei, Masanori 日本複素環化学研究所
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