A Novel Synthesis of Revenine and Related Alkaloids by Means of a Photo-rearrangement Reaction of 4-Alkoxy-2-methylquinoline 1-Oxides

A Novel Synthesis of Revenine and Related Alkaloids by Means of a Photo-rearrangement Reaction of 4-Alkoxy-2-methylquinoline 1-Oxides

フォーマット:

論文

責任表示:

Kaneko, Chikara ; Naito, Toshihiko ; Hashiba, Marimi ; Fujii, Harue ; Somei, Masanori

言語:

英語

出版情報:

Pharmaceutical Society of Japan = 日本薬学会, 1979-01-01

著者名:

掲載情報:

Chemical and Pharmaceutical Bulletin

ISSN:

0009-2363

巻:

27

通号:

8

開始ページ:

1813

終了ページ:

1819

バージョン:

publisher

概要:

Two alkaloids, 1-methyl-4-(3-methylbut-2-enyloxy)-2-quinolone (revenine : IIc) and 4-methoxy-1-methyl-2-quinolone (IIa), were synthesized by means of a photochemical rearrangement reaction of the corresponding 4-alkoxy-2-methylquinoline 1-oxide (Ic and Ia), which were conveniently prepared from 4-chloro-2-methylquinoline 1-oxide (XVII), which in turn is readily obtainable from 2-methylquinoline 1-oxide via the 4-nitrated compound (XVIII). … The mechanism of the photo-rearrangement reaction of 4-alkoxy-2-methylquinoline 1-oxides (Ia-d) in methanol is discussed. 続きを見る

URL:

http://hdl.handle.net/2297/44025

タイトル・著者・出版者が同じ資料

詳細

主題:	synthesis of alkaloids
受理日:	1979-01-01

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1 論文 Studies on the N-Oxides of π-Deficient N-Heteroaromatics. XXXIV. A Novel Synthesis of Substituted Indoles by Photochemical Ring Contraction of 3, … Kaneko, Chikara, Fujii, Harue, Kawai, Shinji, Yamamoto, Atsushi, Hashiba, Kazuhiko, Kimata, Toshihiko, Hayashi, Reiko, … Pharmaceutical Society of Japan = 日本薬学会	7 論文 Preparation and a novel rearrangement reaction of 1, 2, 3, 4-tetrahydro-9-hydroxy-β-carboline, and their applications for the total synthesis of … Somei, Masanori, Noguchi, Koichi, Yamagami, Ryutaro, Kawada, Yumiko, Yamada, Koji, Yamada, Fumio 日本複素環化学研究所
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