Synthesis of (±)-(4aα,6α,7α,7aα)-hexahydro-6-hydroxy-7- methylcyclopenta[c]pyran-3(1H)-one, a structure common to abelialactone, Aglykon A1, and isoboonein

Synthesis of (±)-(4aα,6α,7α,7aα)-hexahydro-6-hydroxy-7- methylcyclopenta[c]pyran-3(1H)-one, a structure common to abelialactone, Aglykon A1, and isoboonein

フォーマット:

論文

責任表示:

Ohba, Masashi ; Haneishi, Tsuyoshi ; Fujii, Tozo

言語:

英語

出版情報:

日本薬学会, 1996-03-01

著者名:

掲載情報:

Chemical & pharmaceutical bulletin

ISSN:

0009-2363

巻:

44

通号:

3

開始ページ:

525

終了ページ:

529

バージョン:

publisher

概要:

Synthesis of (±)-(4aα,6α,7α,7aα)-hexahydro-6-hydroxy-7- methylcyclopenta[c]pyran-3(1h)-one [(±)-1] has been achieved through an 8- step route starting from 6,7-dihydrocyclopenta-1,3-dioxin-5(4H)-one (4). The identities of synthetic (±)-1 with abelialactone, Aglykon A1, and isoboonein permitted the unequivocal assignment of this common structure and the relative stereochemistry to these cyclopentano-monoterpene lactones.

URL:

http://hdl.handle.net/2297/7601

タイトル・著者・出版者が同じ資料

詳細

主題:	1,3-dioxin vinylogous ester; Aglykon A1; abelialactone; carboxyolefination; cyclopentano-monoterpene lactone; isoboonein
受理日:	1996-03-01

類似資料:

1

2

3

4

5

6

7

8

9

10

11

12

1 論文 Syntheses of several cyclopentano-monoterpene lactones using 1,3-dioxin vinylogous ester Ohba, Masashi, Haneishi, Tsuyoshi, Fujii, Tozo 日本薬学会	7 論文 Quinolizidines. XI. Structure determination of the Alangium alkaloid desmethylpsychotrine through synthetic incorporation of ethyl cincholoiponate into … Fujii, Tozo, Ohba, Masashi 日本薬学会
2 論文 Purines. LV. Syntheses and cytokinin activities of some adenine and adenosine derivatives related to 1'-methylzeatin Fujii, Tozo, Ohba, Masashi, Kawamura, Hitoshi, Haneishi, Tsuyoshi, Matsubara, Satoshi 日本薬学会	8 論文 Lactams. XII. Improvements in the Synthesis of Ethyl trans-5-Ethyl-2-oxo-4-piperidineacetate Fujii, Tozo, Yoshifuji, Shigeyuki, Ohba, Masashi 日本薬学会
3 論文 Quinolizidines. XXX. A ready access to the dibenzo[a,f]quinolizidine ring system from 1,2,3,4-tetrahydroquinoline Ohba, Masashi, Shinbo, Y., Toda, M., Fujii, Tozo 日本薬学会	9 論文 Racemic and Chiral Syntheses of Some Indolo[2,3-a] Quinolizidine Alkaloids Through a "Lactim Etherroute" Fujii, Tozo, Ohba, Masashi （株）日本複素環化学研究所
4 論文 Quinolizidines. XV. A Racemic Synthesis of 10-Demethyltubulosine, an Alkaloid from Alangium lamarckii Fujii, Tozo, Ohba, Masashi 日本薬学会	10 論文 Preparatory study for the synthesis of the starfish alkaloid imbricatine. Syntheses of 5-arylthio-3-methyl-L-histidines Ohba, Masashi, Mukaihira, Takafumi, Fujii, Tozo 日本薬学会
5 論文 Lactams. XXII. Preparation of the Enantiomers of 6-Ethoxy-3-ethyl-2,3,4,5-tetrahydro-4-pyridineacetic Acid Ethyl Ester Fujii, Tozo, Ohba, Masashi, Yoneyama, Kaoru, Kizu, Hiroko 日本薬学会	11 論文 Latams. X. The Alkaline Ferricyanide Oxidation of 3-Substituted 1-(3,4-Dimethoxyphenethyl) pyridinium Salts : Effects of Functional Substituents Fujii, Tozo, Ohba, Masashi, Yoshifuji, Shigeyuki, Kirihara, Makoto 日本薬学会
6 論文 Quinolizidines. XVII. A new access to 9,10-dimethoxy- and 8-hydroxy-9,10-dimethoxybenzo[a]quinolizidine-type Alangium alkaloids from 3-acetylpyridine Fujii, Tozo, Ohba, Masashi, Akiyama, Shigeaki 日本薬学会	12 論文 Purines. LXII. Both Enantiomers of N^6-(1,3-Dimetyl-2-butenyl)adenine and Their 9-β-D-Ribofuranosides : Synthesis and Cytokinin Activity Fujii, Tozo, Ohba, Masashi, Kawamura, Hitoshi, Nakashio, Yoshiyuki, Honda, Kei, Matsubara, Satoshi 日本薬学会